Using the model
Symbols, assumptions and limitations
The pH + pOH = 14 relationship assumes dilute aqueous solution at 25 °C.
Worked examples
See the method in practice
Acidic solution
pH 3 corresponds to [H⁺] = 1 × 10⁻³ mol/L.
Basic solution
pOH 2 corresponds to pH 12 and [OH⁻] = 1 × 10⁻² mol/L.
Questions
Frequently asked
Can pH be below 0 or above 14?
Yes in concentrated solutions, although the simple concentration model becomes less accurate because activities matter.
Is neutral pH always 7?
No. Neutrality means [H⁺] = [OH⁻]; the corresponding pH changes with temperature.
Sources & review
Equations and examples are checked against the references below. Results are educational and should be independently verified for safety-critical work.
OpenStax Chemistry — pH and pOHWritten by the STEM Hub editorial team · Reviewed August 11, 2026 · Review methodology