Using the model
Symbols, assumptions and limitations
[HA] is the weak-acid concentration and [A⁻] is its conjugate-base concentration. The approximation is most reliable when both components are appreciable and 0.1 ≤ [A⁻]/[HA] ≤ 10; it uses concentrations in place of activities.
Worked examples
See the method in practice
Equal components
When [A−] = [HA], pH equals pKa.
Twice as much base
A base-to-acid ratio of 2 raises pH by log10(2), about 0.301.
Questions
Frequently asked
Can this calculate a strong-acid pH?
No. It is specifically for a weak acid and its conjugate base.
Should I use concentration or moles?
Concentrations may be replaced by mole amounts only when both components share the same final volume.
Sources & review
Equations and examples are checked against the references below. Results are educational and should be independently verified for safety-critical work.
OpenStax Chemistry — buffer solutionsWritten by the STEM Hub editorial team · Reviewed August 11, 2026 · Review methodology